Optical emission spectroscopy evaluation of exhaust gas temperatures after high current interruption in CO2/O2
DOI:
https://doi.org/10.14311/ppt.2025.2.158Keywords:
high voltage circuit breaker, SF6 alternatives, optical emission spectroscopy, CuFAbstract
In high voltage gas circuit breakers, the pressure buildup necessary for arc extinguishing is partially generated by ablated PTFE nozzle material, which mixes with the insulating gas before being blown through the arcing zone during current interruption. When high short-circuit currents are interrupted, this mixture can retain elevated temperatures for milliseconds as it expands into the circuit breaker’s exhaust volume, and therefore needs to be effectively managed to ensure adequate insulation is maintained. From a circuit breaker design standpoint, this makes accurate knowledge of the exhaust temperature immediately after current zero essential. In this work, two optical emission spectroscopy based temperature determination methods were applied to study the temperature near the exhaust plane exit in a CO2/O2-filled model circuit breaker near current zero. The measured broadband spectra show strong continuum emission from soot particles, in addition to band emission from CuF molecules formed in the exhaust gas. Gray-body spectral fits were performed to estimate temperatures from the continuum emission, which is dominated by the high emissivity soot particles, while temperatures were also obtained via Boltzmann plot evaluation of the emission band intensity ratios. The two methods reveal a temperature mismatch that may suggest slower cooling of the larger soot particles in comparison to the rest of the exhaust gas mixture.
References
M. Seeger, R. Smeets, J. Yan, et al. Recent Trends in Development of High Voltage Circuit Breakers with SF6 Alternative Gases. Plasma Physics and Technology Journal, 4:8–12, 01 2017. doi:10.14311/ppt.2017.1.8.
K. Soni, M. Seeger, and M. Schwinne. Study of exhaust gas temperature in a prototype CO2/C4-FN/O2 circuit breaker using pyrometry. IET Conference Proceedings, 2023, 12 2023. doi:10.1049/icp.2024.0480.
M. Seeger, T. Votteler, S. Pancheshnyi, et al. Breakdown in CO2/O2 and CO2/O2/C2F4 mixtures at elevated temperatures in the range 1000–4000K. Plasma Physics and Technology, 6:39–42, 07 2019. doi:10.14311/ppt.2019.1.39.
Y. Hayashi, M. Watanabe, A. Okino, and E. Hotta. Dynamics of exhaust gas generated by arc extinction. Journal of Applied Physics, 90(10):4966–4972, 11 2001. doi:10.1063/1.1412276.
Y. Tanaka, R. D. Smirnov, A. Y. Pigarov, and M. Rosenberg. Influence of emissivity on behavior of metallic dust particles in plasmas. Physics of Plasmas, 15(7):073704, 07 2008. doi:10.1063/1.2946435.
F. Goulay, P. Schrader, and H. Michelsen. Effect of wavelength dependent emissivity on inferred soot temperatures measured by spectrally resolved laser induced incandescence. Applied Physics B: Lasers and Optics, 100:655–663, 09 2010. doi:10.1007/s00340-010-4119-2.
S. Chippett and W. Gray. The size and optical properties of soot particles. Combustion and Flame, 31:149–159, 1978. doi:10.1016/0010-2180(78)90125-6.
R. E. Steele and H. P. Broida. Chemiluminescence and photoluminescence of CuF. The Journal of Chemical Physics, 69(6):2300–2305, 09 1978. doi:10.1063/1.436939.
F. Ahmed, R. F. Barrow, A. H. Chojnicki, et al. Electronic states of the CuF molecule. I. analysis of rotational structure. Journal of Physics B: Atomic and Molecular Physics, 15(21):3801, nov 1982. doi:10.1088/0022-3700/15/21/006.
C. Dufour, J. Schamps, and R. F. Barrow. Electronic states of the CuF molecule. II. nature of the observed states. Journal of Physics B: Atomic and Molecular Physics, 15(21):3819, nov 1982. doi:10.1088/0022-3700/15/21/007.
J. Delaval and J. Schamps. Ab initio computation of radiative lifetimes of the valence electronic states of CuF. Chemical Physics, 100(1):21–32, 1985. doi:10.1016/0301-0104(85)87020-8.
J. Schamps, J. Delaval, and O. Faucher. A calculation of radiative lifetimes of electronically excited rovibronic levels of CuF. Chemical Physics, 145(1):101–110, 1990. doi:10.1016/0301-0104(90)80121-D.
D. S. Talaga and J. I. Zink. Copper fluoride luminescence during UV photofragmentation of Cu(hfac)2 in the gas phase. Inorganic chemistry, 35 17:5050–5054, 1996. doi:10.1021/ic9515362.
R. Methling, N. Götte, and D. Uhrlandt. Ablation-dominated arcs in CO2 atmosphere—part II: Molecule emission and absorption. Energies, 13(18), 2020. doi:10.3390/en13184720.
J. T. Engelbrecht, D. Kumari, and C. M. Franck. Optical characterization of actively cooled switching arcs in SF6 alternatives. Journal of Physics D: Applied Physics, 58(10):105210, jan 2025. doi:10.1088/1361-6463/ada450.
J. T. Engelbrecht, S. Gortschakow, R. Methling, et al. Study of transient arc properties near current zero in an experimental CO2 high-voltage circuit breaker. Journal of Physics D: Applied Physics, 58(15):155207, mar 2025. doi:10.1088/1361-6463/adbb00.
Downloads
Published
Issue
Section
License
Copyright (c) 2025 J. Engelbrecht, A. Frank, P. Pietrzak

This work is licensed under a Creative Commons Attribution 3.0 Unported License.
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).