Influence of solution properties and gas addition on hydrogen peroxide production by a novel plasma source

Authors

  • Z. Kozakova Brno University of Technology, Faculty of Chemistry
  • F. Krcma Brno University of Technology, Faculty of Chemistry
  • A. Mojzisova Brno University of Technology, Faculty of Chemistry
  • A. Durrova Brno University of Technology, Faculty of Chemistry

DOI:

https://doi.org/10.14311/ppt.2020.3.65

Keywords:

discharge in liquids, hydrogen peroxide, gas addition, solution properties

Abstract

The paper evaluates concentration of hydrogen peroxide produced by a novel pin-hole plasma source in electrolyte solutions with or without gas addition. An effective production rate of hydrogen peroxide is decreased by the increased argon as well as oxygen flow rate through the plasma region. Further, it is enhanced by higher solution conductivity while it is decreased in the strongly basic conditions with the highest pH values.

References

P. J. Bruggemann et al. Plasma-liquid interactions: Areview and roadmap.Plasma Sources Sci. Technol., 25,2016.doi:10.1088/0963-0252/25/5/053002.

S. Samukawa et al. The 2012 plasma roadmap.J.Phys. D Appl. Phys., 45, 2012.doi:10.1088/0022-3727/45/25/253001.

M. J. Kirkpatrick and B. R. Locke. Effects ofplatinum electrode on hydrogen, oxygen, and hydrogenperoxide formation in aqueous phase pulsed coronaelectrical discharge.Ind. Eng. Chem. Res.,45(6):2138–2142, 2006.doi:10.1021/ie0511480.

Ruma and et al. Effects of pulse frequency of inputpower on the physical and chemical properties of pulsedstreamer discharge plasmas in water.J. Phys. D: Appl.Phys., 46(12), 2013.doi:10.1088/0022-3727/46/12/125202.

E. Njatawidjaja et al. Decoloration of electrostaticallyatomized organic dye by the pulsed streamer coronadischarge.J. Electrostatics, 63:353–359, 2005.

P. Šunka et al. Potential applications of pulseelectrical discharges in water.Acta Physica Slovaca,54(2):135–145, 2005.

Z. Stará and F. Krčma. Degradation of organic dyesversus H2O2generation during the dc diaphragmdischarge treatment in water solutions.Acta PhysicaSlovaca, 55(6):515–519, 2005.

F. Krčma and Z. Stará. Hydrogen peroxide generationin quasi-pulsed discharge in water.Proceedings ofECAMPIG XVI, Grenoble, pages 47–48, 2002.

Z. Kozakova et al. Comparison of liquid and liquid-gasphase plasma reactors for discoloration of azo dyes:Analysis of degradation products.Plasma ProcessPolym., 15, 2018.doi:10.1002/ppap.201700178.

F. De Baerdemaeker et al. Characteristics of accapillary discharge produced in electrically conductivewater solution.Plasma Sources Sci. Technol.,16:341–354, 2007.

P. Lukes et al. High power dc diaphragm dischargeexcited in a vapor bubble for the treatment of water.Plasma Chem. Plasma Process., 33(1):83–95, 2013.

A. Y. Nikiforov et al. Physical properties and chemicalefficiency of an underwater dc discharge generated in He,Ar, N2and air bubbles.Plasma Sources Sci. Technol.,20, 2011.doi:10.1088/0963-0252/20/3/034008.

L. Němcová et al. Chemical efficiency of H2O2production and decomposition of organic compoundsunder action of dc underwater discharge in gas bubbles.IEEE Trans. Plasma Sci., 39(3):865–870, 2011.

B. R. Locke et al. Electrohydraulic discharge andnonthermal plasma for water treatment.Ind. Eng. Chem.Res., 45(3):882–905, 2006.doi:10.1021/ie050981u.

P. Lukeš. Water treatment by pulsed streamer coronadischarge; PhD Thesis. Institute of Plasma Physics,Prague, 2001.

F. Krčma. Jet system for plasma generation inliquids. Czech Republic Patent CZ305304B6, 2015.

F. Krčma. Jet system for plasma generation inliquids. European Patent EP3122161B1, 2019.

F. Krčma. Jet system for plasma generation inliquids. Protected construction CZ27173, 2015.

F. Krčma.Jet system for plasma generation in gaseousbubbles in liquids. Protected construction CZ30097, 2016.

F. Krčma et al. Characterization of novel pin-holebased plasma source for generation of discharge in liquidssupplied by DC non-pulsing voltage.Plasma Sources Sci.Technol., 27, 2018.doi:10.1088/1361-6595/aac521.

E. Vyhnánková et al. Influence of electrode materialon hydrogen peroxide generation by DC pinholedischarge.Open Chem., 13:218–223, 2015.doi:10.1515/chem-2015-0054.

G. M. Eisenberg. Colorimetric determination ofhydrogen peroxide.Ind. Eng. Chem., Anal. Ed.,15:327–328, 1943.

A. A. Joshi et al. Formation of hydroxyl radicals,hydrogen peroxide and aqueous electrons by pulsedstreamer corona discharge in aqueous solution.J.Hazard. Mater., 41(1):3–30, 1995.

J. L. Magee and A. Chatterjee. Theoretical aspects ofradiation chemistry. InRadiation Chemistry: Principlesand Applications. VCH Publishers, New York, 1987.

P. Bruggeman et al. Electronic quenching of OH(A)by water in atmospheric pressure plasmas and itsinfluence on the gas temperature determination byOH(A−X) emission.Plasma Sources Sci. Technol., 19,2010.doi:10.1088/0963-0252/19/1/015016.

Z. Machala et al. Formation of ROS and RNS in waterelectro-sprayed through transient spark discharge in airand their bactericidal effects.Plasma Process. Polym.,10:649–659, 2013.doi:doi:0.1002/ppap.201200113.

P. Lukes et al. Aqueous-phase chemistry andbactericidal effects from an air discharge plasma incontact with water: evidence for the formation ofperoxynitrite through a pseudo-second-orderpost-discharge reaction of H2O2and HNO2.PlasmaSources Sci. Technol., 23, 2014.doi:10.1088/0963-0252/23/1/015019.

C. Bradu et al. Degradation of thechlorophenoxyacetic herbicide 2,4-D by plasma-ozonation system.J. Hazard. Mater., 336:52–56, 2017.doi:dx.doi.org/10.1016/j.jhazmat.2017.04.050.70

Downloads

Published

2021-02-25

Issue

Section

Articles