High Power Impulse Magnetron Sputtering of CIGS Thin Films for High Efficiency Thin Film Solar Cells

Authors

  • J. Olejníček
  • Z. Hubička
  • M. Kohout
  • P. Kšírová
  • Š. Kment
  • M. Brunclíková
  • M. Čada
  • S. A. Darveau
  • C. L. Exstrom

Keywords:

CIGS, HiPIMS, emission spectroscopy, thin films, magnetron sputtering

Abstract

In this work CuIn1-xGaxSe2 (CIGS) thin films with three different values of x (0; 0.28; 1) were prepared
by nonreactive sputtering of Cu, In and Ga in HiPIMS (High Power Impulse Magnetron Sputtering) or
DC magnetron and subsequently selenized in an Ar+Se atmosphere. Optical emission spectroscopy
(OES) was used to monitor some basic plasma parameters during sputtering of metallic precursors. CIGS
thin film characteristics were measured using X-ray diffraction (XRD), scanning electron microscopy
(SEM), Raman spectroscopy, energy-dispersive X-ray spectroscopy (EDX) and other techniques.

References

Shafarman W.N., Stolt L., “Cu(InGa)Se2 Solar Cells,” Handbook of Photovoltaic Science and Engineering, ed. by A. Luque and S. Hegedus, John Wiley & Sons, Ltd., (2003) 567-616.

Jackson P., Hariskos D., Wuerz R., Wischmann W., Powalla M., Phys Status Solidi-R 8 (2014) 219-222.

Mattox, D., Handbook of Physical Vapor Deposition (PVD) Processing, Noyes Publ., Park Ridge, NJ, 1998.

Kouznetsov V., Macak K., Schneider J.M., Helmersson U. and Petrov I., Surf Coat Tech 122 (1999) 290-293.

Sittinger V., Szyszka B., Bandorf R., Vergöhl M. and Pflug A., 51st Annual Technical Conference Proceedings of the Society of Vacuum Coaters (2008) 293-301.

Halbe A., Johnson P., Jackson S., Weiss R., Avachat U., Welsh A. and Ehiasarian A.P., Mater Res Soc Proc (2010) 1210-Q06-09.

Olejníček J., Hubička Z., Kšírová P., Kment Š., Brunclíková M., Kohout M., Čada M., Darveau S.A. and Exstrom C.L., J Adv Oxid Technol 16 (2013) 314-319.

Olejníček J., Hubička Z., Virostko P., Deyneka A., Jastrabík L., Chvostová D., Šíchová H. and Pokorný J., Integr Ferroelectr 81 (2006) 227-237.

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Published

2014-08-10

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Articles