Study of ozone destruction reaction on surfaces
DOI:
https://doi.org/10.14311/ppt.2024.2.36Keywords:
ozone, destruction, surface reactionAbstract
The ozone destruction was studied in a quartz cuvette. The time dependence of ozone concentration was measured by absorption spectroscopy. From this time dependence the pseudo first-order rate constant was derived. This rate constant depends on surface condition - the surface concentration of adsorbed oxygen atoms. This surface concentration was changed by reactions of adsorbed oxygen atoms with gaseous molecular oxygen just before the cuvette was filled by ozone. The decrease of atomic oxygen surface concentration leads to the decrease of rate constant for ozone destruction. The measured rate constants were in range 9.0 × 10−5 s−1 to 9.8 × 10−5 s−1.
References
S. Tripathi and T. Hussain. Treatment through Ozone-based technologies. online. Elsevier, 2022. doi:10.1016/B978-0-323-85583-9.00015-6.
C. Ayrault, J. Barrault, N. Blin-Simiand, et al. Oxidation of 2-heptanone in air by a DBD-type plasma generated within a honeycomb monolith supported Pt-based catalyst. Catalysis Today, 89(1-2):75–81, 2004. doi:10.1016/j.cattod.2003.11.042.
W. A. dos Santos Silva, B. S. de Lima, M. I. B. Bernardi, and V. R. Mastelaro. Enhancement of the ozone-sensing properties of ZnO through chemical-etched surface texturing. Journal of Nanoparticle Research, 24(5), 2022. doi:10.1007/s11051-022-05479-3.
U. Tirelli, C. Cirrito, M. Pavanello, et al. Ozone therapy in 65 patients with fibromyalgia: an effective therapy. European Review for Medical and Pharmacological Sciences, 23(4):1786–1788, 2019. doi:10.26355/eurrev_201811_16432.
M. Kopacki, J. Pawlat, B. Skwarylo-Bednarz, et al. Physical crop postharvest storage and protection methods. Agronomy-Basel, 11(1), 2021. doi:10.3390/agronomy11010093.
V. Mazankova, D. Trunec, A. Krzyzankova, et al. Study of oxygen and ozone reactions on surfaces previously treated by ozone. Japanese Journal of Applied Physics, 59(SH), 2020. doi:10.7567/1347-4065/ab5bc0.
U. Kogelschatz. Dielectric-barrier discharges: Their history, discharge physics, and industrial applications. Plasma Chemistry and Plasma Processing, 23(1):1–46, 2003. doi:10.1023/A:1022470901385.
M. Taguchi, Y. Ochiai, R. Kawagoe, et al. Investigation of ozone zero phenomenon using new electrode and surface analysis technique. HAKONE XII Proc., 2009. arXiv:http://neon.dpp.fmph.uniba.sk/hakoneXII/downloads/Book_of_Contributed_Papers.pdf.
S. Suzuki, I. M. Rusinov, K. Teranishi, et al. Re-evaluation of rate coefficients for ozone decomposition by oxygen in wide range of gas pressures (20-1000 Torr) and temperatures (293–423 K). Journal of Physics D: Applied Physics, 51(30), 2018. doi:10.1088/1361-6463/aacd61.
Downloads
Published
Issue
Section
License
Copyright (c) 2024 V. Mazankova, D. Trunec, F. Stanek, F. Krcma

This work is licensed under a Creative Commons Attribution 3.0 Unported License.
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).