Experimental verification of the impact of the air staging on the NOx production and on the temperature profile in a BFB

Authors

  • Matěj Vodička Czech Technical University in Prague, Faculty of Mechanical Engineering, Department of Energy Engineering, Technická 4, 166 07 Prague, Czech Republic https://orcid.org/0000-0003-4854-0340
  • Kristýna Michaliková Czech Technical University in Prague, Faculty of Mechanical Engineering, Department of Energy Engineering, Technická 4, 166 07 Prague, Czech Republic
  • Jan Hrdlička Czech Technical University in Prague, Faculty of Mechanical Engineering, Department of Energy Engineering, Technická 4, 166 07 Prague, Czech Republic
  • Pavel Skopec Czech Technical University in Prague, Faculty of Mechanical Engineering, Department of Energy Engineering, Technická 4, 166 07 Prague, Czech Republic
  • Jitka Jeníková Czech Technical University in Prague, Faculty of Mechanical Engineering, Department of Energy Engineering, Technická 4, 166 07 Prague, Czech Republic

DOI:

https://doi.org/10.14311/AP.2022.62.0400

Keywords:

air staging, bubbling fluidized bed, NOx, SNCR

Abstract

The results of an experimental research on air staging in a bubbling fluidized bed (BFB) combustor are presented within this paper. Air staging is known as an effective primary measure to reduce NOX formation. However, in the case of a number of industrial BFB units, it does not have to be sufficient to meet the emission standards. Then selective non-catalytic reduction (SNCR) can be a cost-effective option for further reduction of the already formed NOX. The required temperature range at the place of the reducing agent injection for an effective application of the SNCR without excessive ammonia slip is above the temperatures normally attained in BFBs. The aim of this paper is to evaluate the impact of staged air injection on the formation of NOX in BFB combustors and to examine the possibility of increasing the freeboard temperature. Several experiments with various secondary/primary air ratios were performed with a constant oxygen concentration in the flue gas. The experiments were carried out using wooden biomass and lignite as fuel in a 30 kWth laboratory scale BFB combustor. Furthermore, the results were verified using a 500 kWth pilot scale BFB unit. The results confirmed that the air staging can effectively move the dominant combustion zone from the dense bed to the freeboard section, and thus the temperatures for an effective application of the SNCR can be obtained.

Downloads

Download data is not yet available.

References

Y. B. Zeldovich, P. Y. Sadovnikov, D. A. Frank-Kamenetskii. Oxidation of Nitrogen in Combustion. Tech. rep., Academy of Sciences of USSR, Institute of Chemical Physics, Moscow-Leningrad, 1947. Transl. by M. Shelef.

I. Glassman, R. A. Yetter. Combustion. Academic Press, Elsevier, 4th edn., 2008.

C. Fenimore. Formation of nitric oxide in premixed hydrocarbon flames. Symposium (International) on Combustion 13(1):373–380, 1971. https://doi.org/10.1016/S0082-0784(71)80040-1.

J. E. Johnsson. Formation and reduction of nitrogen oxides in fluidized-bed combustion. Fuel 73(9):1398–1415, 1994. https://doi.org/10.1016/0016-2361(94)90055-8.

J. Konttinen, S. Kallio, M. Hupa, F. Winter. NO formation tendency characterization for solid fuels in fluidized beds. Fuel 108:238–246, 2013. https://doi.org/10.1016/j.fuel.2013.02.011.

P. Skopec, J. Hrdlička, J. Opatřil, J. Štefanica. NOX emissions from bubbling fluidized bed combustion of lignite coal. Acta Polytechnica 55(4):275–281, 2015. https://doi.org/10.14311/AP.2015.55.0275.

J. A. Miller, C. T. Bowman. Mechanism and modeling of nitrogen chemistry in combustion. Progress in Energy and Combustion Science 15(4):287–338, 1989. https://doi.org/10.1016/0360-1285(89)90017-8.

P. Glarborg, A. D. Jensen, J. E. Johnsson. Fuel nitrogen conversion in solid fuel fired systems. Progress in Energy and Combustion Science 29(2):89–113, 2003. https://doi.org/10.1016/S0360-1285(02)00031-X.

F. Winter, C. Wartha, G. Löffler, H. Hofbauer. The NO and N2O formation mechanism during devolatilization and char combustion under fluidized-bed conditions. Symposium (International) on Combustion 26(2):3325–3334, 1996. https://doi.org/10.1016/S0082-0784(96)80180-9.

K. Svoboda, M. Pohořelý. Influence of operating conditions and coal properties on NOX and N2O emissions in pressurized fluidized bed combustion of subbituminous coals. Fuel 83(7-8):1095–1103, 2004. https://doi.org/10.1016/j.fuel.2003.11.006.

H. Stadler, D. Christ, M. Habermehl, et al. Experimental investigation of NOX emissions in oxycoal combustion. Fuel 90(4):1604–1611, 2011. https://doi.org/10.1016/j.fuel.2010.11.026.

W. Fan, Y. Li, Q. Guo, et al. Coal-nitrogen release and NOX evolution in the oxidant-staged combustion of coal. Energy 125:417–426, 2017. https://doi.org/10.1016/j.energy.2017.02.130.

H. Spliethoff, U. Greul, H. Rüdiger, K. R. Hein. Basic effects on NOX emissions in air staging and reburning at a bench-scale test facility. Fuel 75(5):560–564, 1996. https://doi.org/10.1016/0016-2361(95)00281-2.

K. Sirisomboon, P. Charernporn. Effects of air staging on emission characteristics in a conical fluidized-bed combustor firing with sunflower shells. Journal of the Energy Institute 90(2):316–323, 2017. https://doi.org/10.1016/J.JOEI.2015.12.001.

S. L. Chen, J. A. Cole, M. P. Heap, et al. Advanced NOX reduction processes using -NH and -CN compounds in conjunction with staged air addition. In 22nd Symposium (International) on Combustion, pp. 1135–1145. The Combustion Institute, Pittsburgh, 1988.

J. Hrdlička, P. Skopec, J. Opatřil, T. Dlouhý. Oxyfuel combustion in a bubbling fluidized bed combustor. Energy Procedia 86:116–123, 2016. https://doi.org/10.1016/j.egypro.2016.01.012.

D. Geldart. Types of gas fluidization. Powder Technology 7(5):285–292, 1973. https://doi.org/10.1016/0032-5910(73)80037-3.

D. Kunii, O. Levenspiel. Fluidization Engineering. Elsevier, 2nd edn., 1991. https://doi.org/10.1016/C2009-0-24190-0.

I. G. C. Dryden (ed.). Fluidized-bed combustion, pp. 58–63. Butterworth-Heinemann, 2nd edn., 1982. https://doi.org/10.1016/B978-0-408-01250-8.50014-3.

Downloads

Published

2022-06-30

How to Cite

Vodička, M., Michaliková, K., Hrdlička, J., Skopec, P., & Jeníková, J. (2022). Experimental verification of the impact of the air staging on the NOx production and on the temperature profile in a BFB. Acta Polytechnica, 62(3), 400–408. https://doi.org/10.14311/AP.2022.62.0400