NANOTECHNOLOGY IN THE CULTURAL HERITAGE - INFLUENCE OF NANOSPENSIONS ADOPTED BY NANOPARTICLES OF TiO2 FOR CLEANING THE SURFACE OF HISTORICAL PLASTERS

Authors

  • Klára Kroftová CTU in Prague, Faculty of Civil Engineering, Deparment of Architecture, Prague, Thákurova 7, Czech Republic
  • Markéta Šmidtová CTU in Prague, Faculty of Civil Engineering, Deparment of Building Structures, Prague, Thákurova 7, Czech Republic
  • Ivo Kuřitka Centre of Polymer System,Tomas Bata University in Zlin, třída Tomáše Bati 5678, Czech Republic
  • David Škoda Centre of Polymer System,Tomas Bata University in Zlin, třída Tomáše Bati 5678, Czech Republic

DOI:

https://doi.org/10.14311/CEJ.2017.03.0019

Keywords:

Calcium hydroxide, TiO2, fotocatalysis, nanosuspension, cleaning, antimicrobial

Abstract

The continuous development of nanostructure and the study of physico - chemical processes
in the nanometer range lead to new methods that can slow down the degradation processes of a
work of art, or even restore damage caused, for example, by an inappropriate restoration process.
The use of nanosuspensions based on calcium hydroxide is probably the most widespread
application of nanomaterials in heritage care, especially in the field of hardening of lime building
materials (plaster, limestone, etc.). In combination with titanium dioxide, it should be a successful
suspension in the fight against biological agents, surface contamination or in the protection of UVresistant
building materials.

Downloads

Download data is not yet available.

References

Stonecore, In. Sborník semináře Nanomateriály v památkové péči, STOP, str. 32 – 36

Rathouský, J., 2012. Nanovápno pro konsolidaci porézních materiálů – principy, mechanismy, In.

Sborník semináře Nanomateriály v památkové péči, STOP,str. 28 – 31

Škrdlantová, M. et al. 2012. Laboratorní použití micelárních roztoků a mikroemulzí při čištění

historických materiálů. In. Sborník semináře Nanomateriály v památkové péči, STOP, str. 18 – 22

Baglioni, P. et al. 2012. Nano-Materials for the Conservation and Preservation of Movable and

Immovable Artworks, Progress in Cultural Heritage Preservation – EUROMED 2012, dostupné online:

https://www.researchgate.net/publication/270365605_Nano-

Materials_for_the_Conservation_and_Preservation_of_Movable_and_Immovable_Artworks

Poggi, G. et al. 2010. Hydroxide Nanoparticles for Deacidification and Concomitant Inhibition of Iron-

Gall Ink Corrosion of Paper, Langmuir, 26 (24), pp 19084–19090

Kwitkowska, A. et al. 2014. A.Paper deacidification with the use of magnesium oxide nanoparticles,

Forestry and Wood Technology № 85, p.144-148, dostupné online:

http://agro.icm.edu.pl/agro/element/bwmeta1.element.agro-4b9d7961-05a7-43ed-9339-

f4ba9365a/c/144_Annals85.pdf

Giorgi, R.et al. 2002. Nanotechnologies for Conservation of Cultural Heritage: Paper and Canvas

Deacidification, Langmuir, 18 (21), pp 8198–8203

Graziani, L.et al, 2014. Durability of self-cleaning TiO2 coatings on fired clay brick facades: Effect of

UV exposure and wet &dry cycles, Building and Enviroment, 2014, Vol.71,p.193-203 Dostupný online:

http://www.sciencedirect.com/science/article/pii/S0360132313002904.

Quagliarini, E. et al. 2012. Smart surfaces for architectural heritage: Preliminary results about the

application of TiO2 based coating on travertine, Journal of Cultural Heritage, Vol.13, p.204-209

Quagliarini, E. et al. 2013. Self-cleaning materials on Architectural Heritage: Kompatibility of photoinduced

hydrophibilicity of TiO2 coatingy on stone surfaces, Journal of Cultural Heritage, Vol.14, p.1-7

Gavenda, M. et al. 2005. Consolidación y restauración de revocos esgrafiados en la iglesia

parroquial de Nuestra Señora de la Asunción de Traiguera, Loggia Restauration, Ano VIII, No.18, p.64-69

Liu, T.et al. 2010. Structure stability and corrosion resistance of nano-TiO2 coatings on aluminum in

seawater by a vacuum dip-coating method, Surface and Coatings Technology, Volume 205, Issue 7, p.

–2339

De Filpo, G. et al. 2013. Preventing fungal growth in wood by titanium dioxide nanoparticles,

INTERNATIONAL BIODETERIORATION & BIODEGRADATION, vol. 85 pp. 217–222

Pinho, L. et al. 2013. A novel TiO2–SiO2 nanocomposite converts a very friable stone into a selfcleaning

building material. Applied Surface Science [online]. Vol. 275, s. 389-396 [cit. 2013-11-14]. DOI:

1016/j.apsusc.2012.10.142. ISSN 0169-4332. Dostupný online:

http://www.sciencedirect.com/science/article/pii/S0169433212018831.

Gomez-Ortiz, N. et al. 2013. Antifungal Coatings Based on Ca(OH)(2) Mixed with ZnO/TiO2

Nanomaterials for Protection of Limestone Monuments, ACS APPLIED MATERIALS & INTERFACES Vol. 5

Iss. 5 Pp. 1556-1565

Revuru, A. N. et al.: Photo Catalytic Activity of Anatase TiO2/PVA Film Coated Plate. In: Advanced

Materials Research, 584, 396 (2012).

Allen, G. C. et al.2002. Photocatalytic oxidation of NOx gases using TiO2: a surface spectroscopic

approach. In: Environmental Pollution 120, pp. 415–422.

Wang, H. et al. 2013. Multifunctional nanocomposites for paper conservation, STUDIES IN

CONSERVATION Volume: 58 Issue: 1 Pages: 23-29

Fujishima, A. 2005. Discovery and applications of photocatalysis – Creating a comfortable future by

making use of light energy. In: Japan Nanonet Bulletin, 44th Issue

Hashimoto, K. et al. A. TiO2 Photocatalysis: A Historical Overview and Future Prospects, Japanese

journal of applied physics, vol. 44, No. 12, p. 8269 – 8285, dostupné online:

https://www.jsap.or.jp/jsapi/Pdf/Number14/04_JJAP-IRP.pdf

Bílý, P. et al. Experimentální studie vlivu nanomateriálů na fotokatalytické vlastnosti betonu,

dostupné online: http://stavba.tzb-info.cz/beton-malty-omitky/14178-experimentalni-studie-vlivunanomaterialu-

na-fotokatalyticke-vlastnosti-betonu

Hochmannová, L. et al. 2010. Vliv nanočástic TiO2 a ZnO na fotokatalytické a mikrobiální činky

silikátových nátěrů, Chem. Listy 104, 940-944

Kroftová K., et al. 2017. Synthesis nanolime susepnsions and their potential use in cultural heritage

preservation, konference EASEC-15, October 11-13, Xi´an, China

Downloads

Published

2017-10-31

Issue

Section

Articles

How to Cite

NANOTECHNOLOGY IN THE CULTURAL HERITAGE - INFLUENCE OF NANOSPENSIONS ADOPTED BY NANOPARTICLES OF TiO2 FOR CLEANING THE SURFACE OF HISTORICAL PLASTERS. (2017). Stavební Obzor - Civil Engineering Journal, 26(3). https://doi.org/10.14311/CEJ.2017.03.0019